These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


BIOMARKERS

Molecular Biopsy of Human Tumors

- a resource for Precision Medicine *

119 related articles for article (PubMed ID: 16351100)

  • 1. The high-valent iron-oxo species of polyoxometalate, if it can be made, will be a highly potent catalyst for C-H hydroxylation and double-bond epoxidation.
    Kumar D; Derat E; Khenkin AM; Neumann R; Shaik S
    J Am Chem Soc; 2005 Dec; 127(50):17712-8. PubMed ID: 16351100
    [TBL] [Abstract][Full Text] [Related]  

  • 2. Is the ruthenium analogue of compound I of cytochrome p450 an efficient oxidant? A theoretical investigation of the methane hydroxylation reaction.
    Sharma PK; De Visser SP; Ogliaro F; Shaik S
    J Am Chem Soc; 2003 Feb; 125(8):2291-300. PubMed ID: 12590559
    [TBL] [Abstract][Full Text] [Related]  

  • 3. A proton-shuttle mechanism mediated by the porphyrin in benzene hydroxylation by cytochrome p450 enzymes.
    de Visser SP; Shaik S
    J Am Chem Soc; 2003 Jun; 125(24):7413-24. PubMed ID: 12797816
    [TBL] [Abstract][Full Text] [Related]  

  • 4. Catalysts for monooxygenations made from polyoxometalate: an iron(V)-oxo derivative of the Lindqvist anion.
    Derat E; Kumar D; Neumann R; Shaik S
    Inorg Chem; 2006 Oct; 45(21):8655-63. PubMed ID: 17029376
    [TBL] [Abstract][Full Text] [Related]  

  • 5. Characterization of manganese(V)-oxo polyoxometalate intermediates and their properties in oxygen-transfer reactions.
    Khenkin AM; Kumar D; Shaik S; Neumann R
    J Am Chem Soc; 2006 Dec; 128(48):15451-60. PubMed ID: 17132012
    [TBL] [Abstract][Full Text] [Related]  

  • 6. On the identity and reactivity patterns of the "second oxidant" of the T252A mutant of cytochrome P450cam in the oxidation of 5-methylenenylcamphor.
    Hirao H; Kumar D; Shaik S
    J Inorg Biochem; 2006 Dec; 100(12):2054-68. PubMed ID: 17084458
    [TBL] [Abstract][Full Text] [Related]  

  • 7. What factors affect the regioselectivity of oxidation by cytochrome p450? A DFT study of allylic hydroxylation and double bond epoxidation in a model reaction.
    de Visser SP; Ogliaro F; Sharma PK; Shaik S
    J Am Chem Soc; 2002 Oct; 124(39):11809-26. PubMed ID: 12296749
    [TBL] [Abstract][Full Text] [Related]  

  • 8. Radical clock substrates, their C-H hydroxylation mechanism by cytochrome P450, and other reactivity patterns: what does theory reveal about the clocks' behavior?
    Kumar D; de Visser SP; Sharma PK; Cohen S; Shaik S
    J Am Chem Soc; 2004 Feb; 126(6):1907-20. PubMed ID: 14871124
    [TBL] [Abstract][Full Text] [Related]  

  • 9. Substitution of hydrogen by deuterium changes the regioselectivity of ethylbenzene hydroxylation by an oxo-iron-porphyrin catalyst.
    de Visser SP
    Chemistry; 2006 Oct; 12(31):8168-77. PubMed ID: 16871510
    [TBL] [Abstract][Full Text] [Related]  

  • 10. What factors influence the ratio of C-H hydroxylation versus C=C epoxidation by a nonheme cytochrome P450 biomimetic?
    de Visser SP
    J Am Chem Soc; 2006 Dec; 128(49):15809-18. PubMed ID: 17147391
    [TBL] [Abstract][Full Text] [Related]  

  • 11. Propene activation by the oxo-iron active species of taurine/alpha-ketoglutarate dioxygenase (TauD) enzyme. How does the catalysis compare to heme-enzymes?
    de Visser SP
    J Am Chem Soc; 2006 Aug; 128(30):9813-24. PubMed ID: 16866538
    [TBL] [Abstract][Full Text] [Related]  

  • 12. Gauging the relative oxidative powers of compound I, ferric-hydroperoxide, and the ferric-hydrogen peroxide species of cytochrome P450 toward C-H hydroxylation of a radical clock substrate.
    Derat E; Kumar D; Hirao H; Shaik S
    J Am Chem Soc; 2006 Jan; 128(2):473-84. PubMed ID: 16402834
    [TBL] [Abstract][Full Text] [Related]  

  • 13. Proton-shuffle mechanism of O-O activation for formation of a high-valent oxo-iron species of bleomycin.
    Kumar D; Hirao H; Shaik S; Kozlowski PM
    J Am Chem Soc; 2006 Dec; 128(50):16148-58. PubMed ID: 17165768
    [TBL] [Abstract][Full Text] [Related]  

  • 14. A valence bond modeling of trends in hydrogen abstraction barriers and transition states of hydroxylation reactions catalyzed by cytochrome P450 enzymes.
    Shaik S; Kumar D; de Visser SP
    J Am Chem Soc; 2008 Aug; 130(31):10128-40. PubMed ID: 18616242
    [TBL] [Abstract][Full Text] [Related]  

  • 15. How does product isotope effect prove the operation of a two-state "rebound" mechanism in C-H hydroxylation by cytochrome P450?
    Kumar D; de Visser SP; Shaik S
    J Am Chem Soc; 2003 Oct; 125(43):13024-5. PubMed ID: 14570465
    [TBL] [Abstract][Full Text] [Related]  

  • 16. Probing the Compound I-like reactivity of a bare high-valent oxo iron porphyrin complex: the oxidation of tertiary amines.
    Chiavarino B; Cipollini R; Crestoni ME; Fornarini S; Lanucara F; Lapi A
    J Am Chem Soc; 2008 Mar; 130(10):3208-17. PubMed ID: 18278912
    [TBL] [Abstract][Full Text] [Related]  

  • 17. What is the active species of cytochrome P450 during camphor hydroxylation? QM/MM studies of different electronic states of compound I and of reduced and oxidized iron-oxo intermediates.
    Altun A; Shaik S; Thiel W
    J Am Chem Soc; 2007 Jul; 129(29):8978-87. PubMed ID: 17595079
    [TBL] [Abstract][Full Text] [Related]  

  • 18. Electronic structure and spectroscopy of "superoxidized" iron centers in model systems: theoretical and experimental trends.
    Berry JF; DeBeer George S; Neese F
    Phys Chem Chem Phys; 2008 Aug; 10(30):4361-74. PubMed ID: 18654674
    [TBL] [Abstract][Full Text] [Related]  

  • 19. Is the bound substrate in nitric oxide synthase protonated or neutral and what is the active oxidant that performs substrate hydroxylation?
    de Visser SP; Tan LS
    J Am Chem Soc; 2008 Oct; 130(39):12961-74. PubMed ID: 18774806
    [TBL] [Abstract][Full Text] [Related]  

  • 20. Two-state reactivity in alkane hydroxylation by non-heme iron-oxo complexes.
    Hirao H; Kumar D; Que L; Shaik S
    J Am Chem Soc; 2006 Jul; 128(26):8590-606. PubMed ID: 16802826
    [TBL] [Abstract][Full Text] [Related]  

    [Next]    [New Search]
    of 6.