These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.
2. Reduction of ketones and alkyl iodides by SmI(2) and Sm(II)-HMPA complexes. Rate and mechanistic studies. Prasad E; Flowers RA J Am Chem Soc; 2002 Jun; 124(24):6895-9. PubMed ID: 12059211 [TBL] [Abstract][Full Text] [Related]
3. Mechanistic study of samarium diiodide-HMPA initiated 5-exo-trig Ketyl-Olefin coupling: the role of HMPA in post-electron transfer steps. Sadasivam DV; Antharjanam PK; Prasad E; Flowers RA J Am Chem Soc; 2008 Jun; 130(23):7228-9. PubMed ID: 18479133 [TBL] [Abstract][Full Text] [Related]
5. A first oxalamidino complex of samarium via reduction-coupling of carbodiimine: synthesis and molecular structure of [eta4-C2(NR)4][(MeC5H4)2Sm(HMPA)]2.2THF (R = Pr i, Cy). Deng M; Yao Y; Zhang Y; Shen Q Chem Commun (Camb); 2004 Dec; (23):2742-3. PubMed ID: 15568095 [TBL] [Abstract][Full Text] [Related]
6. Creating carbon-carbon bonds with samarium diiodide for the synthesis of modified amino acids and peptides. Ebran JP; Jensen CM; Johannesen SA; Karaffa J; Lindsay KB; Taaning R; Skrydstrup T Org Biomol Chem; 2006 Oct; 4(19):3553-64. PubMed ID: 16990928 [TBL] [Abstract][Full Text] [Related]
7. The Use of Ureates as Activators for Samarium Diiodide. McDonald CE; Ramsey JD; McAtee CC; Mauck JR; Hale EM; Cumens JA J Org Chem; 2016 Jul; 81(14):5903-14. PubMed ID: 27322641 [TBL] [Abstract][Full Text] [Related]
9. Lithium Bromide/Water as Additives in Dearomatizing Samarium-Ketyl (Hetero)Arene Cyclizations. Rao CN; Bentz C; Reissig HU Chemistry; 2015 Nov; 21(45):15951-4. PubMed ID: 26368916 [TBL] [Abstract][Full Text] [Related]
10. Asymmetric conjugate reductions with samarium diiodide: asymmetric synthesis of (2S,3R)- and (2S,3S)-[2-2H,3-2H]-leucine-(S)-phenylalanine dipeptides and (2S,3R)-[2-(2)H,3-2H]-phenylalanine methyl ester. Davies SG; Rodriguez-Solla H; Tamayo JA; Cowley AR; Concellon C; Garner AC; Parkes AL; Smith AD Org Biomol Chem; 2005 Apr; 3(8):1435-47. PubMed ID: 15827639 [TBL] [Abstract][Full Text] [Related]
11. Structure and Energetics of the Samarium Diiodide-HMPA Complex in Tetrahydrofuran. Shotwell JB; Sealy JM; Flowers RA J Org Chem; 1999 Jul; 64(14):5251-5255. PubMed ID: 34237851 [TBL] [Abstract][Full Text] [Related]
12. Beta-elimination reactions by using samarium diiodide. Concellón JM; Rodríguez-Solla H Chem Soc Rev; 2004 Nov; 33(9):599-609. PubMed ID: 15592625 [TBL] [Abstract][Full Text] [Related]
13. A New Samarium Diiodide Induced Reaction: Intramolecular Attack of Ketyl Radical Anions on Aryl Substituents with Formation of 1,4-Cyclohexadiene Derivatives. Dinesh CU; Reissig HU Angew Chem Int Ed Engl; 1999 Mar; 38(6):789-791. PubMed ID: 29711804 [TBL] [Abstract][Full Text] [Related]
14. Regioselective samarium diiodide induced couplings of carbonyl compounds with 1,3-diphenylallene and alkoxyallenes: a new route to 4-hydroxy-1-enol ethers. Hölemann A; Reissig HU Chemistry; 2004 Oct; 10(21):5493-506. PubMed ID: 15372682 [TBL] [Abstract][Full Text] [Related]
15. Medium-sized carbocycles by samarium diiodide-induced carbonyl-alkene cyclizations. Saadi J; Lentz D; Reissig HU Org Lett; 2009 Aug; 11(15):3334-7. PubMed ID: 19583214 [TBL] [Abstract][Full Text] [Related]
16. Radical cyclization by ipso substitution of the methoxy group: considerable effect of HMPA on samarium-mediated cyclization. Ohno H; Wakayama R; Maeda S; Iwasaki H; Okumura M; Iwata C; Mikamiyama H; Tanaka T J Org Chem; 2003 Jul; 68(15):5909-16. PubMed ID: 12868925 [TBL] [Abstract][Full Text] [Related]
17. Highly diastereoselective samarium diiodide induced cyclizations of new 3-substituted indole derivatives. Beemelmanns C; Reissig HU Org Biomol Chem; 2009 Nov; 7(21):4475-80. PubMed ID: 19830298 [TBL] [Abstract][Full Text] [Related]
18. SmI2-mediated reduction of gamma,gamma-difluoro-alpha,beta-enoates with application to the synthesis of functionalized (Z)-fluoroalkene-type dipeptide isosteres. Otaka A; Watanabe J; Yukimasa A; Sasaki Y; Watanabe H; Kinoshita T; Oishi S; Tamamura H; Fujii N J Org Chem; 2004 Mar; 69(5):1634-45. PubMed ID: 14987023 [TBL] [Abstract][Full Text] [Related]
19. The role of ligand displacement in SmII-HMPA-based reductions. Prasad E; Knettle BW; Flowers RA J Am Chem Soc; 2004 Jun; 126(22):6891-4. PubMed ID: 15174857 [TBL] [Abstract][Full Text] [Related]
20. Beyond samarium diiodide: vistas in reductive chemistry mediated by lanthanides(II). Szostak M; Procter DJ Angew Chem Int Ed Engl; 2012 Sep; 51(37):9238-56. PubMed ID: 22893612 [TBL] [Abstract][Full Text] [Related] [Next] [New Search]