601 related articles for article (PubMed ID: 22035197)
1. Is it homogeneous or heterogeneous catalysis derived from [RhCp*Cl2]2? In operando XAFS, kinetic, and crucial kinetic poisoning evidence for subnanometer Rh4 cluster-based benzene hydrogenation catalysis.
Bayram E; Linehan JC; Fulton JL; Roberts JA; Szymczak NK; Smurthwaite TD; Özkar S; Balasubramanian M; Finke RG
J Am Chem Soc; 2011 Nov; 133(46):18889-902. PubMed ID: 22035197
[TBL] [Abstract][Full Text] [Related]
2. Industrial Ziegler-type hydrogenation catalysts made from Co(neodecanoate)2 or Ni(2-ethylhexanoate)2 and AlEt3: evidence for nanoclusters and sub-nanocluster or larger Ziegler-nanocluster based catalysis.
Alley WM; Hamdemir IK; Wang Q; Frenkel AI; Li L; Yang JC; Menard LD; Nuzzo RG; Özkar S; Yih KH; Johnson KA; Finke RG
Langmuir; 2011 May; 27(10):6279-94. PubMed ID: 21480617
[TBL] [Abstract][Full Text] [Related]
3. Iridium Ziegler-type hydrogenation catalysts made from [(1,5-COD)Ir(mu-O2C8H15)](2) and AlEt3: spectroscopic and kinetic evidence for the Ir(n) species present and for nanoparticles as the fastest catalyst.
Alley WM; Hamdemir IK; Wang Q; Frenkel AI; Li L; Yang JC; Menard LD; Nuzzo RG; Ozkar S; Johnson KA; Finke RG
Inorg Chem; 2010 Sep; 49(17):8131-47. PubMed ID: 20681520
[TBL] [Abstract][Full Text] [Related]
4. Is it homogeneous or heterogeneous catalysis? Compelling evidence for both types of catalysts derived from [Rh(eta5-C5Me5)Cl2]2 as a function of temperature and hydrogen pressure.
Hagen CM; Widegren JA; Maitlis PM; Finke RG
J Am Chem Soc; 2005 Mar; 127(12):4423-32. PubMed ID: 15783225
[TBL] [Abstract][Full Text] [Related]
5. In situ formed "weakly ligated/labile ligand" iridium(0) nanoparticles and aggregates as catalysts for the complete hydrogenation of neat benzene at room temperature and mild pressures.
Bayram E; Zahmakiran M; Ozkar S; Finke RG
Langmuir; 2010 Jul; 26(14):12455-64. PubMed ID: 20536218
[TBL] [Abstract][Full Text] [Related]
6. Development plus kinetic and mechanistic studies of a prototype supported-nanoparticle heterogeneous catalyst formation system in contact with solution: Ir(1,5-COD)Cl/gamma-Al2O3 and its reduction by H2 to Ir(0)n/gamma-Al2O3.
Mondloch JE; Wang Q; Frenkel AI; Finke RG
J Am Chem Soc; 2010 Jul; 132(28):9701-14. PubMed ID: 20575521
[TBL] [Abstract][Full Text] [Related]
7. In situ formed catalytically active ruthenium nanocatalyst in room temperature dehydrogenation/dehydrocoupling of ammonia-borane from Ru(cod)(cot) precatalyst.
Zahmakiran M; Ayvalı T; Philippot K
Langmuir; 2012 Mar; 28(11):4908-14. PubMed ID: 22356554
[TBL] [Abstract][Full Text] [Related]
8. Is it homogeneous or heterogeneous catalysis? Identification of bulk ruthenium metal as the true catalyst in benzene hydrogenations starting with the monometallic precursor, Ru(II)(eta 6-C6Me6)(OAc)2, plus kinetic characterization of the heterogeneous nucleation, then autocatalytic surface-growth mechanism of metal film formation.
Widegren JA; Bennett MA; Finke RG
J Am Chem Soc; 2003 Aug; 125(34):10301-10. PubMed ID: 12926954
[TBL] [Abstract][Full Text] [Related]
9. Monitoring supported-nanocluster heterogeneous catalyst formation: product and kinetic evidence for a 2-step, nucleation and autocatalytic growth mechanism of Pt(0)n formation from H2PtCl6 on Al2O3 or TiO2.
Mondloch JE; Yan X; Finke RG
J Am Chem Soc; 2009 May; 131(18):6389-96. PubMed ID: 19379011
[TBL] [Abstract][Full Text] [Related]
10. Evidence that imidazolium-based ionic ligands can be metal(0)/nanocluster catalyst poisons in at least the test case of iridium(0)-catalyzed acetone hydrogenation.
Ott LS; Campbell S; Seddon KR; Finke RG
Inorg Chem; 2007 Nov; 46(24):10335-44. PubMed ID: 17975891
[TBL] [Abstract][Full Text] [Related]
11. Reactivity of chemisorbed oxygen atoms and their catalytic consequences during CH4-O2 catalysis on supported Pt clusters.
Chin YH; Buda C; Neurock M; Iglesia E
J Am Chem Soc; 2011 Oct; 133(40):15958-78. PubMed ID: 21919447
[TBL] [Abstract][Full Text] [Related]
12. Nanoclusters in catalysis: a comparison of CS(2) catalyst poisoning of polyoxoanion- and tetrabutylammonium-stabilized 40 +/- 6 A Rh(0) nanoclusters to 5 Rh/Al(2)O(3), including an analysis of the literature related to the CS(2) to metal stoichiometry issue.
Hornstein BJ; Aiken JD; Finke RG
Inorg Chem; 2002 Mar; 41(6):1625-38. PubMed ID: 11896733
[TBL] [Abstract][Full Text] [Related]
13. Model Ziegler-type hydrogenation catalyst precursors, [(1,5-COD)M(mu-O2C8H15)]2 (M = Ir and Rh): synthesis, characterization, and demonstration of catalytic activity en route to identifying the true industrial hydrogenation catalysts.
Alley WM; Girard CW; Ozkar S; Finke RG
Inorg Chem; 2009 Feb; 48(3):1114-21. PubMed ID: 19127998
[TBL] [Abstract][Full Text] [Related]
14. A Pt-cluster-based heterogeneous catalyst for homogeneous catalytic reactions: X-ray absorption spectroscopy and reaction kinetic studies of their activity and stability against leaching.
Li Y; Liu JH; Witham CA; Huang W; Marcus MA; Fakra SC; Alayoglu P; Zhu Z; Thompson CM; Arjun A; Lee K; Gross E; Toste FD; Somorjai GA
J Am Chem Soc; 2011 Aug; 133(34):13527-33. PubMed ID: 21721543
[TBL] [Abstract][Full Text] [Related]
15. Hydrogenation of arenes over silica-supported catalysts that combine a grafted rhodium complex and palladium nanoparticles: evidence for substrate activation on Rh(single-site)-Pd(metal) moieties.
Barbaro P; Bianchini C; Dal Santo V; Meli A; Moneti S; Psaro R; Scaffidi A; Sordelli L; Vizza F
J Am Chem Soc; 2006 May; 128(21):7065-76. PubMed ID: 16719488
[TBL] [Abstract][Full Text] [Related]
16. The use of imidazolium ionic liquids for the formation and stabilization of ir0 and rh0 nanoparticles: efficient catalysts for the hydrogenation of arenes.
Fonseca GS; Umpierre AP; Fichtner PF; Teixeira SR; Dupont J
Chemistry; 2003 Jul; 9(14):3263-9. PubMed ID: 12866070
[TBL] [Abstract][Full Text] [Related]
17. Dimethylammonium hexanoate stabilized rhodium(0) nanoclusters identified as true heterogeneous catalysts with the highest observed activity in the dehydrogenation of dimethylamine-borane.
Zahmakiran M; Ozkar S
Inorg Chem; 2009 Sep; 48(18):8955-64. PubMed ID: 19702246
[TBL] [Abstract][Full Text] [Related]
18. At the frontier between heterogeneous and homogeneous catalysis: hydrogenation of olefins and alkynes with soluble iron nanoparticles.
Rangheard C; de Julián Fernández C; Phua PH; Hoorn J; Lefort L; de Vries JG
Dalton Trans; 2010 Sep; 39(36):8464-71. PubMed ID: 20714614
[TBL] [Abstract][Full Text] [Related]
19. Synthesis, spectroscopy, and catalytic properties of cationic organozirconium adsorbates on "super acidic" sulfated alumina. "Single-site" heterogeneous catalysts with virtually 100 active sites.
Nicholas CP; Ahn H; Marks TJ
J Am Chem Soc; 2003 Apr; 125(14):4325-31. PubMed ID: 12670255
[TBL] [Abstract][Full Text] [Related]
20. Bidentates versus monodentates in asymmetric hydrogenation catalysis: synergic effects on rate and allosteric effects on enantioselectivity.
Norman DW; Carraz CA; Hyett DJ; Pringle PG; Sweeney JB; Orpen AG; Phetmung H; Wingad RL
J Am Chem Soc; 2008 May; 130(21):6840-7. PubMed ID: 18454526
[TBL] [Abstract][Full Text] [Related]
[Next] [New Search]
