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  • Title: Enantioselective parallel synthesis using polymer-supported chiral Co(salen) complexes.
    Author: Peukert S, Jacobsen EN.
    Journal: Org Lett; 1999 Oct 21; 1(8):1245-8. PubMed ID: 10825975.
    Abstract:
    [formula: see text] The kinetic resolution of epoxides with phenols catalyzed by a polymer-supported Co(salen) complex is applied to the first enantioselective catalytic synthesis of parallel libraries. The corresponding 1-aryloxy-2-alcohols are obtained in high yield, purity, and enantiomeric excess. Further elaboration with diversity elements provides highly efficient access to important classes of pharmacologically active compounds.
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