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  • Title: Toward creation of a universal NMR database for the stereochemical assignment of acyclic compounds: proof of concept.
    Author: Lee J, Kobayashi Y, Tezuka K, Kishi Y.
    Journal: Org Lett; 1999 Dec 30; 1(13):2181-4. PubMed ID: 10836073.
    Abstract:
    [formula: see text] Using the C.5-C.10 portion of the oasomycin class of natural products, the reliability and usefulness of an NMR database for the stereochemical assignment of acyclic compounds has been demonstrated. The predicted relative stereochemistry based on the NMR database has unambiguously been established via synthesis.
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