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  • Title: Synthesis of C(3) benzofuran-derived bisaryl quaternary centers: approaches to diazonamide A.
    Author: Fuerst DE, Stoltz BM, Wood JL.
    Journal: Org Lett; 2000 Nov 02; 2(22):3521-3. PubMed ID: 11082024.
    Abstract:
    [reaction: see text] Two complementary strategies for the synthesis of the diazonamide A bisaryl quaternary center are described. The first strategy relies upon an extremely facile tandem cyclopropanation/ring-opening sequence, which has proven amenable to chiral catalysis to provide enantioenriched material. The second strategy relies upon a more concise alkylation route ideal for material advancement.
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