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  • Title: Synthesis of (+/-)-epoxysorbicillinol using a novel cyclohexa-2,5-dienone with synthetic applications to other sorbicillin derivatives.
    Author: Pettus LH, Van De Water RW, Pettus TR.
    Journal: Org Lett; 2001 Mar 22; 3(6):905-8. PubMed ID: 11263912.
    Abstract:
    A novel route to epoxysorbicillinol as well as dimers of sorbicillin is reported. The synthesis is-in principle-amenable to enantioselectivity. The key step is an oxidative dearomatization to produce a stable and highly malleable p-quinol intermediate, which undergoes a highly diastereoselective epoxidation.
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