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  • Title: Asymmetric synthesis of quaternary alpha-amino phosphonates using sulfinimines.
    Author: Davis FA, Lee S, Yan H, Titus DD.
    Journal: Org Lett; 2001 May 31; 3(11):1757-60. PubMed ID: 11405704.
    Abstract:
    The addition of lithium diethylphosphonate to enantiopure ketosulfinimines is highly diastereoselective (>95%), affording the first examples of quaternary alpha-alkyl alpha-amino (arylmethyl)phosphonates.
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