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  • Title: Photoinduced formation of beta-oxy-alpha,alpha-disubstituted-alpha-amino acid derivatives from ketoximes.
    Author: Torrente S, Alonso R.
    Journal: Org Lett; 2001 Jun 28; 3(13):1985-7. PubMed ID: 11418030.
    Abstract:
    [reaction: see text] The first intermolecular radical addition onto ketoxime ethers is described. beta-Oxygenated quaternary alpha-amino acid derivatives IotaIota were obtained upon irradiation of alpha-alkoxycarbonyl ketoxime ethers Iota in the presence of suitable alpha-alkoxy carbon radical precursors and a sensitizer.
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