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  • Title: Enantioselective rhodium(I)-catalyzed hydrogenation of trifluoromethyl ketones.
    Author: Kuroki Y, Sakamaki Y, Iseki K.
    Journal: Org Lett; 2001 Feb 08; 3(3):457-9. PubMed ID: 11428038.
    Abstract:
    [figure: see text] The asymmetric hydrogenation of trifluoromethyl ketones to yield chiral alpha-trifluoromethyl alcohols with enantiomeric excesses up to 98% was achieved in the presence of chiral rhodium-(amidephosphine-phosphinite) complexes.
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