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  • Title: Kinetic resolution in palladium-catalyzed asymmetric allylic alkylations by a P,O ligand system.
    Author: Gilbertson SR, Lan P.
    Journal: Org Lett; 2001 Jul 12; 3(14):2237-40. PubMed ID: 11440588.
    Abstract:
    [reaction: see text] Through the investigation of peptide-based phosphine oxazoline ligands, a simple P,O ligand system was developed. This system provides palladium complexes that are capable of a very high degree of kinetic resolution of 1,3-diphenylprop-2-enyl acetate. The isolated palladium complex was synthesized, characterized, and determined to be an effective procatalyst.
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