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Title: Toward the creation of NMR databases in chiral solvents for assignments of relative and absolute stereochemistry: scope and limitation. Author: Hayashi N, Kobayashi Y, Kishi Y. Journal: Org Lett; 2001 Jul 12; 3(14):2249-52. PubMed ID: 11440591. Abstract: [structure: see text] Three additional NMR databases, 1-3, in a chiral solvent are presented. The C.21-C.38 portion of oasomycin A is used to demonstrate the scope and limitation of the universal NMR database approach in a chiral solvent for assignment of relative and absolute stereochemistry without degradation and/or derivatization.[Abstract] [Full Text] [Related] [New Search]