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  • Title: Synthesis of the amino sugar from C-1027.
    Author: Semmelhack MF, Jiang Y, Ho D.
    Journal: Org Lett; 2001 Jul 26; 3(15):2403-6. PubMed ID: 11463327.
    Abstract:
    [reaction: see text] The amino sugar side chain (2) from C-1027Chr was synthesized in 12 steps from mannose. The key reactions are an internal displacement by nitrogen to introduce the cis amino group at C-4 and the methylation of an enolate at C-5.
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