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  • Title: Synthesis of the diazonamide A macrocyclic core via a Dieckmann-type cyclization.
    Author: Vedejs E, Zajac MA.
    Journal: Org Lett; 2001 Aug 09; 3(16):2451-4. PubMed ID: 11483032.
    Abstract:
    [reaction: see text] Suzuki coupling of 18 and 30 affords 9 as an interconverting mixture of two atropisomers. Treatment with LDA at -23 degrees C affords the macrocyclic ketone 8 in 57% yield.
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