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  • Title: Preparation of deuterium-labeled cocaine and benzoylecgonine.
    Author: Bosin TR, Garbrecht FC, Raymond MG.
    Journal: Res Commun Chem Pathol Pharmacol; 1975 Jul; 11(3):405-11. PubMed ID: 1153884.
    Abstract:
    The preparation of deuterium-labeled cocaine and benzoylecgonine by a site-specific method is reported. This method involves the reductive dehalogenation of appropriately substituted derivatives by a NaBD4 - PdCl2 system. By the judicious choice of halogen-substituted aromatic systems, a wide variety of specifically deuterated compounds of biological interest can be prepared.
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