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  • Title: Biaxial model of the surface anchoring of bent-core smectic liquid crystals.
    Author: Maclennan JE, Clark NA, Walba DM.
    Journal: Phys Rev E Stat Nonlin Soft Matter Phys; 2001 Sep; 64(3 Pt 1):031706. PubMed ID: 11580354.
    Abstract:
    In synclinically tilted smectic phases, bent-core liquid crystal molecules aligned with the director in the plane of a cell boundary will, in general, have their molecular (bow) planes parallel to the boundary, normal to it, or at a well-defined intermediate orientation. A model describing the interaction of such bent-core (banana-shaped) molecules with planar surfaces that distinguishes energetically between molecules lying flat on the surface and those oriented edge on is given by a biaxial modification of the uniaxial surface anchoring expression used for chiral smectics of rod-shaped molecules. When combined with a field-induced straightening of the smectic layers, the model provides a mechanism for the transition from an analog to a bistable director response observed electro-optically in the ferroelectric banana-shaped material (R,S)-MHOBOW.
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