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  • Title: Toward the creation of NMR databases in chiral solvents: bidentate chiral NMR solvents for assignment of the absolute configuration of acyclic secondary alcohols.
    Author: Kobayashi Y, Hayashi N, Kishi Y.
    Journal: Org Lett; 2002 Feb 07; 4(3):411-4. PubMed ID: 11820892.
    Abstract:
    The absolute configuration of acyclic secondary alcohols can be established from analysis of the chemical shift behaviors of the adjacent carbons in bidentate chiral solvents (R,R)- and (S,S)-1d as formulated in the boxed illustration.
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