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  • Title: Stereoselective synthesis of vancosamine and saccharosamine glycals via tungsten-catalyzed alkynol cycloisomerization.
    Author: Cutchins WW, McDonald FE.
    Journal: Org Lett; 2002 Mar 07; 4(5):749-52. PubMed ID: 11869118.
    Abstract:
    [reaction: see text] A stereoselective synthesis of the C-3 branched amino glycals of vancosamine and saccharosamine is described that features a tungsten carbonyl catalyzed cycloisomerization of the corresponding alkynyl alcohol.
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