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  • Title: From Lobry de Bruyn to enzyme-catalyzed ammonia channelling: molecular studies of D-glucosamine-6P synthase.
    Author: Teplyakov A, Leriche C, Obmolova G, Badet B, Badet-Denisot MA.
    Journal: Nat Prod Rep; 2002 Feb; 19(1):60-9. PubMed ID: 11902440.
    Abstract:
    This review summarizes the state of knowledge on D-glucosamine-6P synthesis catalyzed by glucosamine-6P synthase. The mechanisms of L-glutamine hydrolysis, ammonia transfer and fructose-6P conversion into D-glucosamine-6P are analyzed with the E. coli enzyme in light of recent X-ray structures. With 92 references this paper covers the literature up to June 2001 and emphasizes the potential implication of the mammalian glucosamine-6P synthase in type 2 diabetes.
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