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  • Title: Electrochemical imination of sulfoxides using N-aminophthalimide.
    Author: Siu T, Yudin AK.
    Journal: Org Lett; 2002 May 30; 4(11):1839-42. PubMed ID: 12027627.
    Abstract:
    [reaction: see text] A novel electrochemical sulfoxide imination process is described. Our approach starts with a highly selective nitrene transfer from N-aminophthalimide to a variety of sulfoxides. This oxidative treatment is followed by reductive N-N bond cleavage under the controlled current conditions, which leads to a range of parent NH sulfoximines. In addition to solving the challenging problem of removing the N-phthalimido group, the overall process avoids the use of toxic oxidants and metal additives.
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