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  • Title: Nitrate controls on iron and arsenic in an urban lake.
    Author: Senn DB, Hemond HF.
    Journal: Science; 2002 Jun 28; 296(5577):2373-6. PubMed ID: 12089437.
    Abstract:
    Aquatic ecosystems are often contaminated by multiple substances. Nitrate, a common aquatic pollutant, strongly influenced the cycling of arsenic (As) under anoxic conditions in urban Upper Mystic Lake (Massachusetts, USA) by oxidizing ferrous iron [Fe(II)] to produce As-sorbing particulate hydrous ferric oxides and causing the more oxidized As(V), which is more particle-reactive than As(III) under these conditions, to dominate. This process is likely to be important in many natural waters.
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