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  • Title: Productive trapping of NAD-type radicals. Non-biomimetic reduction of pyridinium salts.
    Author: Lavilla R, Bernabeu MC, Brillas E, Carranco I, Díaz JL, Llorente N, Rayo M, Spada A.
    Journal: Chem Commun (Camb); 2002 Apr 21; (8):850-1. PubMed ID: 12123010.
    Abstract:
    One-electron reduction of pyridinium salts (NAD+ analogues) generates dihydropyridyl radicals which may then be engaged in radical addition processes to regioselectively form gamma-substituted dihydropyridines.
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