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  • Title: First total synthesis of a novel monoterpenoid isoquinoline alkaloid, (+/-)-alangine.
    Author: Takayama H, Arai M, Kitajima M, Aimi N.
    Journal: Chem Pharm Bull (Tokyo); 2002 Aug; 50(8):1141-3. PubMed ID: 12192157.
    Abstract:
    The structure including the stereochemistry of a novel monoterpenoid isoquinoline alkaloid, alangine, was confirmed by total synthesis via N-acyliminium cyclization to construct the isoquinoline skeleton and reductive cleavage of vinyl epoxide with Pd(0) catalyst.
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