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  • Title: Daphmanidin A, a novel hexacyclic alkaloid from Daphniphyllum teijsmanii.
    Author: Kobayashi J, Ueno S, Morita H.
    Journal: J Org Chem; 2002 Sep 06; 67(18):6546-9. PubMed ID: 12201780.
    Abstract:
    A novel alkaloid with an unprecedented fused-hexacyclic skeleton, daphmanidin A (1), and a new pentacyclic alkaloid, daphmanidin B (2), have been isolated from the leaves of Daphniphyllum teijsmanii, and the structures were elucidated on the basis of spectroscopic data. The relative and absolute stereochemistry of 1 was determined by combination of NOESY correlations and a modified Mosher method.
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