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  • Title: Highly enantioselective hydrogenation of enol acetates catalyzed by Ru-TunaPhos complexes.
    Author: Wu S, Wang W, Tang W, Lin M, Zhang X.
    Journal: Org Lett; 2002 Dec 12; 4(25):4495-7. PubMed ID: 12465921.
    Abstract:
    [reaction: see text] The chiral disphosphines with tunable dihedral angles (TunaPhos) have been used for asymmetric hydrogenation of enol acetates and dihedral-angle-dependent enantioselectivities were observed. C2-TunaPhos has been proved to be effective for Ru-catalyzed asymmetric hydrogenation of electron-deficient and other enol acetates.
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