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  • Title: Synthesis of aminocyclohexitol via carbon-carbon bond-forming radical cyclization of oxime ether.
    Author: Miyabe H, Nishiki A, Naito T.
    Journal: Chem Pharm Bull (Tokyo); 2003 Jan; 51(1):100-3. PubMed ID: 12520139.
    Abstract:
    The stannyl radical mediated-cyclization of oxime ether, derived from D-glucose, gave the aminocyclohexitol derivative. Stereoselective C-C bond forming cyclization proceeded via favorable conformers minimizing A(1,3)-strain between the oxime ether group and alpha-substituents.
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