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  • Title: Total synthesis of (-)-21-isopentenylpaxilline.
    Author: Smith AB, Cui H.
    Journal: Org Lett; 2003 Feb 20; 5(4):587-90. PubMed ID: 12583776.
    Abstract:
    [structure: see text] The total synthesis of (-)-21-isopentenylpaxilline (1) has been achieved. Key elements of the synthesis include the stereocontrolled construction of the advanced eastern hemisphere (-)-5, a highly efficient union of the eastern and western fragments (-)-5 and 4, respectively, exploiting our 2-substituted indole synthesis, and a new protocol for the construction of ring C.
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