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  • Title: Novel thermal reaction of Fischer carbene complexes with imines: synthesis of beta-methoxy allylic amine derivatives.
    Author: Sangu K, Kagoshima H, Fuchibe K, Akiyama T.
    Journal: Org Lett; 2002 Oct 31; 4(22):3967-9. PubMed ID: 12599504.
    Abstract:
    [formula: see text] Alkyl-substituted chromium Fischer carbene complexes were found to react with various N-tosylimines to give beta-methoxy allylic amine derivatives under thermal conditions. This result is essentially distinct from the photochemical outcome in which beta-lactam derivatives are obtained.
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