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  • Title: P[N(i-Bu)CH2CH2]3N: a versatile ligand for the Pd-catalyzed amination of aryl chlorides.
    Author: Urgaonkar S, Nagarajan M, Verkade JG.
    Journal: Org Lett; 2003 Mar 20; 5(6):815-8. PubMed ID: 12633079.
    Abstract:
    [reaction: see text] Palladium-catalyzed amination reactions of aryl chlorides with amines proceeded in the presence of the bicyclic triaminophosphine P[N(i-Bu)CH(2)CH(2)](3)N to afford the corresponding arylamines in good to excellent yields. Electron-poor, electron-neutral, and electron-rich aryl chlorides all participated with equal ease.
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