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  • Title: Samarium diiodide-induced couplings of carbonyl compounds with methoxyallene leading to 4-hydroxy 1-enol ethers.
    Author: Hölemann A, Reissig HU.
    Journal: Org Lett; 2003 May 01; 5(9):1463-6. PubMed ID: 12713299.
    Abstract:
    A surprising samarium diiodide-induced coupling reaction of carbonyl compounds with methoxyallene provided 4-hydroxy 1-enol ethers, which are versatile synthetic building blocks. In this coupling reaction, methoxyallene serves as an acrolein equivalent, which cannot directly be employed. [reaction: see text]
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