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  • Title: Regioselective synthesis of the tricyclic core of lateriflorone.
    Author: Tisdale EJ, Li H, Vong BG, Kim SH, Theodorakis EA.
    Journal: Org Lett; 2003 May 01; 5(9):1491-4. PubMed ID: 12713306.
    Abstract:
    An efficient synthetic approach to the tricyclic core 8 of lateriflorone is described. Essential to the synthesis was the implementation of a biomimetic tandem Claisen/Diels-Alder reaction that produced the desired tricyclic scaffold as a single isomer. A rationalization of the excellent regio and stereoselectivity of this transformation is also proposed. [reaction: see text]
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