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  • Title: Asymmetric synthesis of the four possible fagomine isomers.
    Author: Takahata H, Banba Y, Ouchi H, Nemoto H, Kato A, Adachi I.
    Journal: J Org Chem; 2003 May 02; 68(9):3603-7. PubMed ID: 12713367.
    Abstract:
    The asymmetric synthesis of fagomine and its congeners 1-4 has been achieved by catalytic ring-closing metathesis (RCM). The synthesis involved the construction of the piperidene-type chiral building block 5 followed by dihydroxylation, starting from the d-serine-derived Garner aldehyde 6.
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