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  • Title: Highly enantioselective hydrolysis of alicyclic meso-epoxides with a bacterial epoxide hydrolase from Sphingomonas sp. HXN-200: simple syntheses of alicyclic vicinal trans-diols.
    Author: Chang D, Wang Z, Heringa MF, Wirthner R, Witholt B, Li Z.
    Journal: Chem Commun (Camb); 2003 Apr 21; (8):960-1. PubMed ID: 12744319.
    Abstract:
    Hydrolysis of N-benzyloxycarbonyl-3,4-epoxy-pyrrolidine and cyclohexene oxide with the epoxide hydrolase of Sphingomonas sp. HXN-200, respectively, gave the corresponding vicinal trans-diols in high ee and yield, representing the first example of enantioselective hydrolysis of a meso-epoxide with a bacterial epoxide hydrolase.
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