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  • Title: De novo asymmetric bio- and chemocatalytic synthesis of saccharides - stereoselective formal O-glycoside bond formation using palladium catalysis.
    Author: Comely AC, Eelkema R, Minnaard AJ, Feringa BL.
    Journal: J Am Chem Soc; 2003 Jul 23; 125(29):8714-5. PubMed ID: 12862452.
    Abstract:
    A novel integrated bio- and chemocatalytic approach to the de novo catalytic asymmetric synthesis of saccharides has been developed. Acetoxypyranones obtained enantiopure by enzymatic resolution have been shown to undergo highly stereoselective palladium-catalyzed formal O-glycoside bond formation. The combination of these protocols can be applied to the iterative asymmetric catalytic synthesis of saccharides.
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