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  • Title: Coordination-driven self-assembly of supramolecular cages: heteroatom-containing and complementary trigonal prisms.
    Author: Kryschenko YK, Seidel SR, Muddiman DC, Nepomuceno AI, Stang PJ.
    Journal: J Am Chem Soc; 2003 Aug 13; 125(32):9647-52. PubMed ID: 12904031.
    Abstract:
    The self-assembly of three nanoscopic prisms of approximate size 1 x 4 nm is reported. Tetrahedral carbon, silicon, and phosphorus were used as structure-defining elements in these coordination-based cages. A carbon-based assembly completes a pair of nanoscopic complementary 3-D structures. The formation of the structures is supported by multinuclear NMR, ESI FT-ICR mass spectrometry, and elemental analysis data.
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