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  • Title: Triterpenoid saponins from Medicago hispida.
    Author: Mahato SB.
    Journal: Phytochemistry; 1991; 30(10):3389-93. PubMed ID: 1367788.
    Abstract:
    Soyasaponin III has been characterized and the structure of a new triterpenoid saponin, hispidacin, has been elucidated as soyasapogenol B-3-O-alpha-L-rhamnopyranopyranosyl(1----2)- beta-D-glucopyranosyl(1----2)-beta-D-glucuronopyranoside by a combination of fast-atom bombardment mass spectrometry, 13C NMR spectroscopy, and some chemical transformations. Mechanism of transformation of soyasapogenol B to soyasapogenols D, and F has also been rationalized.
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