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  • Title: Stereoselective total synthesis of wheat flour ceramide dihexoside.
    Author: Koike K, Mori M, Ito Y, Nakahara Y, Ogawa T.
    Journal: Agric Biol Chem; 1990 Nov; 54(11):2931-9. PubMed ID: 1368649.
    Abstract:
    A plant glycosphingolipid, O-(beta-D-mannopyranosyl)-(1----4)-O-(beta-D-glucopyranosyl)-(1----1)-(2 S,3S,4R)-4-hydroxy-N-tetracosanoylsphinganine 1, and the stereoisomer, O-(alpha-D-mannopyranosyl)-(1----4)-O-(beta-d-glucopyranosyl)-(1----1)-( 2S,3S,4R)-4-hydroxy-N-tetracosanoylsphinganine 6, were synthesized in a stereo- and regio-controlled way.
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