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  • Title: Accelerating effect of a proton on the reduction of CO2 dissolved in water under acidic conditions. Isolation, crystal structure, and reducing ability of a water-soluble ruthenium hydride complex.
    Author: Hayashi H, Ogo S, Abura T, Fukuzumi S.
    Journal: J Am Chem Soc; 2003 Nov 26; 125(47):14266-7. PubMed ID: 14624561.
    Abstract:
    A water-soluble hydride complex [(eta6-C6Me6)RuII(bpy)H]+ {1, bpy = 2,2'-bipyridine} serves as a robust reducing agent for the reduction of CO2 in water in a pH range of about 3-5 at ambient temperature under stoichiometric conditions. The structure of 1 was unequivocally determined by X-ray analysis. The mechanism of acid-catalyzed reduction of CO2 promoted by 1 in water under acidic conditions is disclosed.
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