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Title: Synthesis of the putative structure of eupomatilone-6. Author: Gurjar MK, Cherian J, Ramana CV. Journal: Org Lett; 2004 Feb 05; 6(3):317-9. PubMed ID: 14748582. Abstract: [reaction: see text] The synthesis of eupomatilone-6 (1) has been achieved by using Suzuki coupling, Sharpless asymmetric dihydroxylation, and intramolecular Horner-Wadsworth-Emmons reactions. The spectroscopic studies carried out on synthetic eupomatilone-6 do not agree with those reported for the natural product, and therefore revision of the assigned structure is warranted.[Abstract] [Full Text] [Related] [New Search]