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  • Title: Model systems for flavoenzyme activity: interplay of hydrogen bonding and aromatic stacking in cofactor redox modulation.
    Author: Gray M, Goodman AJ, Carroll JB, Bardon K, Markey M, Cooke G, Rotello VM.
    Journal: Org Lett; 2004 Feb 05; 6(3):385-8. PubMed ID: 14748599.
    Abstract:
    [structure: see text] A model system has been developed to study the synergy between aromatic stacking and hydrogen bonding in the binding of a flavin derivative. The results show that the identity of both the hydrogen bonding and pi-stacking units strongly determine the overall receptor affinity for flavin in both the oxidized and radical anion forms.
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