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  • Title: Suzuki cross-couplings of unactivated secondary alkyl bromides and iodides.
    Author: Zhou J, Fu GC.
    Journal: J Am Chem Soc; 2004 Feb 11; 126(5):1340-1. PubMed ID: 14759182.
    Abstract:
    The capacity to employ unactivated alkyl electrophiles as coupling partners will markedly increase the already exceptional utility of metal-catalyzed cross-coupling processes. This communication describes the development of a method that achieves the first Suzuki reactions of unactivated secondary alkyl bromides and iodides. The ability to couple readily available, easy-to-handle boronic acids is an attractive feature of this catalyst system.
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