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Title: Introduction of functionalized C1, C2, and C3 units to imines through the dimethylzinc-air-initiated radical addition. Author: Yamada K, Yamamoto Y, Maekawa M, Tomioka K. Journal: J Org Chem; 2004 Mar 05; 69(5):1531-4. PubMed ID: 14987007. Abstract: Introduction of functionalized C1, C2, and C3 units to imines was achieved by using the dimethylzinc-air-initiated alpha-alkoxyalkyl radical addition as a key reaction. The addition to a C[double bond]N double bond chemoselectively occurred in the presence of a C[double bond]O double bond, which is one of the advantages of this radical addition reaction over ionic addition reactions.[Abstract] [Full Text] [Related] [New Search]