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  • Title: Total synthesis of the eight diastereomers of the syn-anti-syn phytoprostanes F1 types I and II.
    Author: El Fangour S, Guy A, Despres V, Vidal JP, Rossi JC, Durand T.
    Journal: J Org Chem; 2004 Apr 02; 69(7):2498-503. PubMed ID: 15049650.
    Abstract:
    Syntheses of the eight enantiomerically pure diastereomers of the syn-anti-syn phytoprostanes F(1) types I and II are described starting from D- and L-glucose. Key steps include Wittig coupling, Horner Wadsworth Emmons (HWE) reactions, and enantioselective reduction of alpha,beta-unsaturated ketones.
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