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  • Title: Rhodium-catalyzed imination of sulfoxides and sulfides: efficient preparation of N-unsubstituted sulfoximines and sulfilimines.
    Author: Okamura H, Bolm C.
    Journal: Org Lett; 2004 Apr 15; 6(8):1305-7. PubMed ID: 15070323.
    Abstract:
    The Rh(II)-catalyzed imination of sulfoxides and sulfides using [Rh(2)(OAc)(4)] as a catalyst and trifluoroacetamide or sulfonylamides in combination with iodobenzene diacetate and magnesium oxide affords sulfoximines and sulfilimines, respectively, in a stereospecific manner. [reaction: see text]
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