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  • Title: Development of a recyclable fluorous chiral phase-transfer catalyst: application to the catalytic asymmetric synthesis of alpha-amino acids.
    Author: Shirakawa S, Tanaka Y, Maruoka K.
    Journal: Org Lett; 2004 Apr 29; 6(9):1429-31. PubMed ID: 15101759.
    Abstract:
    [structure: see text] A recyclable fluorous chiral phase-transfer catalyst was synthesized and successfully applied for the catalytic asymmetric synthesis of both natural and unnatural alpha-amino acids. The reaction involves alkylation of a glycine derivative followed by extractive recovery of the chiral phase-transfer catalyst using fluorous solvent.
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