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  • Title: Stereoselective total synthesis of antitumor macrolide (+)-rhizoxin D.
    Author: Jiang Y, Hong J, Burke SD.
    Journal: Org Lett; 2004 Apr 29; 6(9):1445-8. PubMed ID: 15101763.
    Abstract:
    [structure: see text] A convergent, stereoselective total synthesis of the macrolide antitumor agent rhizoxin D is described. (+)-DIPCl-promoted asymmetric aldol reaction, Evans-Tishchenko 1,3-diol synthesis, modified Julia coupling, and Horner-Wadsworth-Emmons reactions are featured.
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