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Title: Formal synthesis of (+/-)-guanacastepene A: a tandem ring-closing metathesis approach. Author: Boyer FD, Hanna I, Ricard L. Journal: Org Lett; 2004 May 27; 6(11):1817-20. PubMed ID: 15151422. Abstract: A concise route to a key intermediate in the total synthesis of guanacastepene A is described. The main features include the simultaneous construction of the seven- and six-membered rings, using a tandem ring-closing metathesis and a stereoselective introduction of the oxygenated function at the C5 position. [reaction: see text][Abstract] [Full Text] [Related] [New Search]