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  • Title: Synthesis and X-ray crystal structures of the first antimony and bismuth calixarene complexes.
    Author: Liu L, Zakharov LN, Rheingold AL, Hanna TA.
    Journal: Chem Commun (Camb); 2004 Jul 07; (13):1472-3. PubMed ID: 15216336.
    Abstract:
    The reaction of the monosodium salt of p-tert-butylcalix[4]arene (But)C4) with 2 equivalents of SbCl3 provides ButC4(SbCl)2 and the first bismuth calixarene complex was prepared by treatment of p-tert-butylcalix[8]arene (ButC8) with Bi[N(SiMe3)2]3 in toluene.
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