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  • Title: Evidence for a NiI active species in the catalytic cross-coupling of alkyl electrophiles.
    Author: Anderson TJ, Jones GD, Vicic DA.
    Journal: J Am Chem Soc; 2004 Jul 07; 126(26):8100-1. PubMed ID: 15225035.
    Abstract:
    Addition of terpyridine to (TMEDA)Ni(CH3)2 results in the high-yield formation of (terpyridyl)NiMe (3). This NiI organometallic complex was found to be capable of transferring its methyl group to iodocyclohexane to produce methylcyclohexane in high yield. Compound 3 can also serve as an initiator for the catalytic cross-coupling of alkyl electrophiles performed under Negishi-like conditions.
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