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  • Title: Ring synthesis by stereoselective, methylene-free enyne cross metathesis.
    Author: Kulkarni AA, Diver ST.
    Journal: J Am Chem Soc; 2004 Jul 07; 126(26):8110-1. PubMed ID: 15225040.
    Abstract:
    Tandem enyne metathesis between 1-alkynes and 1,5-cyclooctadiene or all-cis-1,4-polybutadiene resulted in a direct, one-step ring synthesis of cyclohexadienes by methylene-free metathesis. The use of methylene-free metathesis conditions provided apparent Z-selectivity in the intermolecular enyne metathesis step.
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